Firetube Boiler

The next stage in the process is to boil water and make steam. The goal is to make the heat flow as completely as possible from the heat source to the water. The water is confined in a restricted space heated by the fire. The steam produced has lower density than the water and therefore will accumulate at the highest level in the vessel; its temperature will remain at boiling point and will only increase as pressure increases. Steam in this state (in equilibrium with the liquid water which is being evaporated within the boiler) is named "saturated steam". For example, saturated steam at atmospheric pressure boils at 100 °C (212 °F).

Saturated steam taken from the boiler may contain entrained water droplets, however a well designed boiler will supply virtually "dry" saturated steam, with very little entrained water. Continued heating of the saturated steam will bring the steam to a "superheated" state, where the steam is heated to a temperature above the saturation temperature, and no liquid water can exist under this condition.

Physical layout of the four main devices used in the Rankine cycle

Most reciprocating steam engines of the 19th century used saturated steam, however modern steam power plants universally use superheated steam which allows higher steam cycle efficiency.